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Stereoretentive Addition of N-tert-Butylsulfonyl-alpha-Amido Silanes to Aldehydes, Ketones, alpha,beta-Unsaturated Esters, and Imines

机译：N-叔丁基磺酰基-α-氨基硅烷与醛，酮，α，β-不饱和酯和亚胺的立体定向加成

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Enantioenriched N-tert-butylsulfonyl-alpha-amido si-lanes were successfully reacted with aldehydes, ketones, imines, and alpha,beta-unsaturated esters in the presence of a sub-stoichiometric amount of CsF (0.5 equiv) in 1,2-di-methoxyethane (DME) at -20 degrees C to afford the corresponding coupling products with up to 89% enantiospecificity in a retentive manner.

机译：在亚化学计量的CsF（0.5当量），1,2-二甲基硅氧烷的存在下，富含对映体的N-叔丁基磺酰基-α-酰胺基硅烷成功地与醛，酮，亚胺和α，β-不饱和酯反应在-20摄氏度下以二甲氧基乙烷（DME）的形式保留相应的偶联产物，其对映体特异性最高可达89％。

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Mita, Tsuyoshi; Saito, Keisuke; Sugawara, Masumi; Sato, Yoshihiro;
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年度 2016
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1. Stereoretentive Addition of N-tert-Butylsulfonyl-alpha-Amido Silanes to Aldehydes, Ketones, alpha,beta-Unsaturated Esters, and Imines [J] . Mita Tsuyoshi, Saito Keisuke, Sugawara Masumi, Chemistry, an Asian journal . 2016,第10期

机译：在醛，酮，α，β-不饱和酯和亚胺中的立体entive加入N-叔丁基磺酰基-α-氨基甲酰基-MIDO硅烷和亚胺
2. New Application of Bromotrimethylsilane:Elaboration of Aldehydes/Ketones into Homologous alpha,beta-Unsaturated Esters via beta-Hydroxy Esters [J] . Suresh C.Suri, Jacob C.Marcischak Synthetic Communications . 2005,第3期

机译：溴三甲基硅烷的新应用：通过β-羟基酯将醛/酮加工成同源的α，β-不饱和酯
3. Anionic four-electron donor-based palladacycles as catalysts for addition reactions of arylboronic acids with alpha,beta-unsaturated ketones, aldehydes, and alpha-ketoesters [J] . He P, Lu Y, Dong CG, Organic letters . 2007,第2期

机译：阴离子型基于四电子给体的palladacycles，用作芳基硼酸与α，β-不饱和酮，醛和α-酮酸酯的加成反应的催化剂
4. 1,4-Addition of Arylboronic Acids to p-Aryl-alpha,beta-unsaturated Ketones and Esters Catalyzed by a Rhodium(I)-chiraphos Complex [C] . Takashi Nishikata, Tetsuji Iyama, Hiroto Tachikawa Symposium on Organometallic Chemistry . 2006

机译：1,4-加入芳基硼酸至p-芳基-α，β-不饱和酮和由铑（I）催化的酯 - 富铬络合物
5. Molecular Design for a Novel Organotin Hydride and Ferric Chloride Mediated Michael Addition of Dicarboxylic Acid Esters to alpha,beta-Unsaturated Ketones. [D] . Deka, Dibakar Chandra. 2010

机译：新型有机锡氢化物和氯化铁介导的二羧酸酯向α，β-不饱和酮的迈克尔加成反应的分子设计。
6. Metal-Free Catalytic Enantioselective C–B Bond Formation: (Pinacolato)boron Conjugate Additions to αβ-Unsaturated Ketones Esters Weinreb Amides and Aldehydes Promoted by Chiral N-Heterocyclic Carbenes [O] . Hao Wu, Suttipol Radomkit, Jeannette M. O’Brien, -1

机译：金属 - 催化免不对称C-B键的形成：（频哪醇）硼共轭加成到αβ不饱和酮酯酰胺的Weinreb和醛手性N-杂环卡宾推荐
7. Conjugate Additions of Grignard Reagents to alpha, beta-Unsaturated Esters. XIII. Additions of cis-trans-Isomeric But-2-enoic and 2-Methylbut-2-enoic Esters. [O] . Ture Kindt-Larsen, Vibeke Bitsch, Inger Grete Krogh Andersen, 1963

机译：将GRIGNARD试剂的共轭添加至α，β-不饱和酯。 XIII。加入顺式 - 反式异构除去-2-烯型和2-甲基丁酯-2-烯酯。
8. 9-Borabicyclo(3.3.1)nonane as a Highly Selective Reducing Agent for the Facile Conversion of alpha, beta-Unsaturated Aldehydes and Ketones to the Corresponding Allylic Alcohols in the Presence of Other Functional Groups. [R] . Krishnamurthy, S., Brown, H. C. 1975

机译：9-Borabicyclo（3.3.1）壬烷作为高选择性还原剂，用于在其他官能团存在下将α，β-不饱和醛和酮轻易转化为相应的烯丙醇。

Stereoretentive Addition of N-tert-Butylsulfonyl-alpha-Amido Silanes to Aldehydes, Ketones, alpha,beta-Unsaturated Esters, and Imines

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